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A00132.gifComponents in a lacquer (Topic: 14020)

A wet lacquer consists of the following main components:

1. Resin

2. Crosslinking agents

3. Pigments

4. Solvents

5. Extenders

6. Additives

A powder coating is produced without solvents, and all the components have to be on non-volatile basis. That means a difference in available components for production of a powder coating and a wet lacquer. In the presentation of the lacquer components powder coating composition will be emphasised because powder coatings are much more used on profiles than wet lacquers.

The resin is the most important component in a lacquer, and the part which gives the name of the lacquer (e.g. epoxy lacquer). The dry lacquer coating consists of resin, plus pigments, and additives, which are dispersed in the resin. The resin should give good adhesion to the surface of the substrate. Wear and weathering resistance, chemical resistance, ductility, gloss, and hardness are factors dependent on the type of resin.

Crosslinking agents or hardeners are needed to get curing of some types of lacquers. If no crosslinking agent is used, only physical drying of the lacquer coating will occur. No crosslinking will take place, and mechanical properties and chemical resistance will be very poor. Polyamide is an example of a crosslinking agent, which is used in a epoxy resin.

Pigments are mainly added to give the right colour and covering power. They can also influence other properties like hardness, chemical resistance, protection against UV-radiation, or corrosion resistance. The amount and choice of pigments in a lacquer are important regarding gloss, colour retention, vapour permeability, and corrosion protection. A high pigment volume concentration gives a brittle coating with poor chemical resistance, but a good protection against UV-radiation. Active pigments improve the corrosion properties of the lacquer.

There are a wide range of both organic and inorganic pigments, even if not all of them are suitable for powder coatings.

The major types of pigments being used in powder coating products are:

- inorganic pigments

- organic pigments

- carbon black

- titanium dioxide

Solvents are used to give the lacquer the right consistency for the different application methods. During the application and drying the solvents evaporate. Some lacquers can be applied without solvents or with very small amounts of solvents. The most well- known type is called powder lacquers. A powder lacquer is made by mixing dry components together, melting to a homogeneous mass, cooling/solidification and milling of the lacquer chips to the right powder size.

Extenders are chemically inert, natural or artificially manufactured inorganic compounds, which do not have any colouring and hiding properties.

Extenders are mainly used to reduce the price of the final lacquer coating, but they also bring the following positive effects:

- reduction of coating sagging by giving "body" to the lacquer

- coating reinforcement against abrasion or wear

- reduction of degrading effect of UV-light

- improvement of corrosion resistance

- improvement of moisture resistance

Barium sulphate, calcium carbonate and aluminium silicates are the three main extenders which are used in powder coatings. China clay, French chalk or similar inert white pigments are used in liquid lacquers.

Additives are used in liquid and powder lacquers to produce special finishes or to ameliorate their properties.

The seven main types of employed additives for powder lacquers are:

- accelerators

- gloss agents

- dry flow agents

- flow agents

- matting agents

- texturing agents

- wax